Category Hydrogen Energy

From the inception of the Industrial Revolution several core ingredients enabled the transformation and growth of industry.  Among these core building blocks of the Industrial Revolution namely: access to risk capital, visionary entrepreneurs, available labor, technology, resources and energy.  Technology and energy play a crucial role in not only growing industry but enable scale.   Technology can open new markets and provide advantage through product differentiation and economies of scale.  Energy is literally the fuel that scales operations.

Today technology, built from knowledge and data, is how companies compete. Energy now emerges as even more integral in scaling operations. Just as James Watt developed the first steam powered engine in 1606 commencing the Industrial Revolution, it was the access to available coal with the use of the steam powered pump, invented by Thomas Savery in 1698, that allowed greater access to coal that gave scale to industry.

Most recently, the pending transaction of Salesforce’s (CRM) acquisition of Slack (WORK) after acquiring Tableau last year serves as a reference in valuing the importance of technology is to sustaining market value.  The market value of seven companies accounts for 27% of the approximately $31.6 trillion for the S&P 500.  Evaluating the industry and market impact of innovative technologies can be viewed through the lens of stock valuations, particularly as it applies to mergers and acquisitions.  This article reviews the companies and the technologies from the perspective of market sales opportunity and the economic impact of the technologies based on the price/performance disruption to the industry.

So why are we focusing on energy and data today?  Energy, predominantly hydrocarbon fuels such as oil, natural gas and even coal is how people heat their homes and buildings, facilitate transportation, and generate electricity to run lights, computers, machines and equipment. In addition, there is substantial investment focus on the digital economy, Environmental and Social Governance (ESG), and innovative technologies. A common thread among these themes is energy and data.

Data and Energy are the pillars of the digital economy. Energy efficiency can reduce carbon emissions, thereby improve ESG sustainability initiatives. Innovative technologies around energy and data are opening new markets and processes from formulating new business models to structuring and operating businesses.

The climate imperative and investing in energy infrastructure and environmental ESGs are predicted on energy efficiency and relevant performance metrics to evaluate investment allocation decisions. Therefore, our initial emphasis begins with a background on energy consumption with focus on electric consumption trends, carbon footprint, Green House Gas (GHG) emissions, sustainability, electric grid resilience, and technologies that impact energy including Electric Vehicles (EV), energy storage, and Autonomous Driving (AD).  Data technologies encompass cloud architecture, Software as a Service (SaaS), Machine Learning (ML) analytics, and the importance of data as the digital transformation gives rise to the digital economy. 

Digital Economy Performance Metrics

Before we dive into the financial and competitive analysis, let’s review business models that are disruptive to the status quo. That is are innovative technologies capable of rapid scale and efficiency gains that change the economics of the market and business profitability.  In addition, disruptive events, driven primarily by technology, often appear as waves as the adoption of innovative technologies expands through the market.

Prominent technological waves such as the personal computer (PC), followed by the internet and smartphones and most recently social media and cloud computer all manifested themselves in engendering new business models and creating new market opportunities that dramatically changed the status quo among leading companies at the time. We will use the internet and mobile technology waves to explain how the introduction of innovative technologies offering vastly improved means of commerce enabled the development of new services that changed the business landscape.

Most recent advances in technology appear as waves and give rise to new business models and markets. The internet is one example. The internet enables the connection and process of communication over a new channel.  The internet allowed one-to-one and one to many communications and the ability to engage, transact and scale using a digital platform that tremendously lowered the cost of engagement. Scale is among the most important attributes of the internet because the cost of digital replication is close to zero.

Mobile and smartphones began a new era in the digital world.  The smartphone allowed a large portion of the world to interact with the internet for the first time on a mobile device. The mobile wave provided platform that enabled the introduction of a host of new business models.  The introduction of the Apple iPhone gave way to several new services and industries all from your cell phone.

Let’s review the business model impact of innovative technologies as it applies to cost structure.

Cost Structure and Disruptive Innovation

As explained by ARK Investment Management’s Catherine Wood, the rate of cost decline can be used as a proxy for evaluating the disruptive impact of innovative technology. Cost structure improves as unit production expands. As first postulated by Theodore Wright, an aerospace engineer, who postulated that “for every accumulated doubling of aircraft production, costs fell by about 20 percent”. Wright’s Law as it is now known is also called the Learning Curve or Experience Curve and it is found across industries that experience different rates of declining costs.

What is important from the perspective of investment firms such as Ark is that the magnitude of disruptive impact can be gleaned from these declining cost curves. Revenue growth can then be correlated from these declining cost curves. Essentially, demand elasticity and future sales can be derived from the rate of product cost declines. 

This is why price/performance and scientific metrics play an important role in evaluating products, services and company competitive positions. For example, the average cellular price per gigabyte (GB) of data is approximately $12.37 in 2020 according to Small business trends. Another example in science, is the physical performance of an LED light assessed by lumens the light output to the amount of energy consumed in watts such as lumens/watt (Lm/W). These metrics are points in time. For more context, the changes over time and magnitude of change provide insight into inflection points, trends, patterns and relationships.

As devices become complex, encompassing separate processors for communications, computing, power, video and various sensors, it is the integration and orchestration of the overall device performance that becomes of greater value to the user. So, price/performance, scientific understanding and economics become more attuned to relationships among these varied and interdependent components.

TAM Expansion Attribute

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After reviewing oil data from the Energy Information Administration (EIA), Global Petroleum Consumption , it may be helpful to put energy consumption into perspective. Most of us are quite familiar with alternative energy such as solar and wind, but the reality is, even if solar and wind could supply all of electric energy needs, the majority of our energy needs is still predicated on access to oil.

While industry experts and scientist debate whether more drilling will ameliorate the energy challenge we face, let’s look at a couple of data points. Figure 1 US Oil Field Oil Production and Drilling Rigs – illustrates that higher drilling activity as measured by Baker Hughes Rig Count data does not necessarily correlate to more oil production as measured by US Oil Field Production by the EIA. Higher drilling activity does not produce more oil.

Figure 1 US Oil Field Production and Drilling Rigs
Source: Energy Information Administration and Baker Hughes research

Despite the large investment in drilling rigs that more than doubled from 1,475 in 1974 to over 3,100 in 1982, US oil production remained relatively flat. Moreover, even the most recent drilling expansion activity that again more than doubled from 1,032 rigs in 2003 to over 2,300 rigs in 2009, resulted in relatively flat oil production, suggesting that on the margin unit oil production per drilling rig was declining. Perhaps even more disturbing is that the most recent drilling activity in the US was accomplished through extensive use of technology. Seismic imaging technology is being used to better locate oil deposits and horizontal drilling technologies are employed to more efficiently extract the oil, yet oil production still lags historic levels. While on the margin, newly announced offshore drilling could add to domestic oil production, extraction costs of oil will continue to rise adding to further oil price increases.

However, what is most profound is our dependence on oil for most of our energy needs similar to how wood was used for fuel construction material during the 1300’s and 1600’s. If we translate energy consumption into equivalent measuring units such as kilowatt-hours, we can compare and rank energy consumption. Although electricity is captured through consumption of several fuels most notably coal, a comparison of energy usage between oil and electric provides an interesting perspective.

Figure 2 Energy Perspective – provides a simple comparison of the consumption of oil and electricity measured in gigawatt-hours (one million kilowatt hours). A barrel of oil is equivalent to approximately 5.79 million BTUs or 1,699 KWH and the US consumed approximately 19.5 million barrels per day equating to 12 million gigawatt-hours a year. The US uses 4 million gigawatt-hours of electric energy annually. The critical point is that even if solar and wind supplied all of our electric energy needs, it would still only comprise 30% of our total energy needs. Therefore, without an energy strategy that facilitates migration towards a substitute for oil, particularly for transportation, we are missing the boat.

Figure 2 Energy Perspective
Source: Energy Information Administration and Green Econometrics research

It’s not all doom and gloom. Technologies are advancing, economies of scale are driving costs lower, and the economics for new approaches to transportation are improving. From hybrids and electric vehicles benefiting from advances lithium-ion batteries to hydrogen fuel cell vehicles getting 600 miles on a tank of fuel. These advanced technologies could mitigate our addiction to oil, however, without formulating an energy strategy directing investments towards optimizing the economics, energy efficiency, environment, and technology, we may miss the opportunity.

The bottom line is that oil is supply-constrained as there are no readily available substitutes, and therefore, without a means to rapidly expand production; supply disruptions could have a pernicious and painful impact on our economy, national security, and welfare.

With the infinite wisdom of the White House and U.S. Congress, food prices are now directly tied to the price oil. The price of corn-based ethanol is now determined by the price of gasoline that it substitutes in motor vehicles and that price is established by supply and demand for oil. The price of gasoline at your local gas station or convenience store is based on the price of oil. And now that the price of corn is rising because it is tied directly to oil, the price of other grains and subsequently, prices along the entire food chain are rising.

Corn Prices have increased 166% since 2005. The rising price of corn that is used to produce corn ethanol is causing farmers to direct their limited resources to grow more corn, which means other grains such as wheat or soy become scarce and their prices rise. The growing scarcity of grains for food products is raising price across the food chain. Developing a renewable energy solutions based on diverting food as a substitute for expensive gasoline forces food supplies to become scare and expensive.

It is the supply and demand for gasoline and diesel fuels that establishes the price at the pump. When corn ethanol is substituted for gasoline, prices tend to gravitate towards a mean price that continues to rise to keep pace with the escalating price of crude oil now over $110 per barrel. Corn prices are inextricably linked to oil prices and in turn; corn prices impact other grain prices that means it cost more to feed your family or to feed livestock and forces those prices higher.

The rise in corn prices is illustrated in Figure 1.

Figure 1 Corn Prices

Irrespective of the timing of Peak Oil, a long-term energy strategy is required. The days of cheap oil are over. Remember how oil production in Alaska helped ease the U.S demand for foreign oil a couple of decades ago. Oil production in Alaska declined by nearly 75 percent from its peak in 1987 according a Washington Post article back in 2005. In November 2007, the Petroleum News indicated production in Alaska is expected to decline further in the future. The U.S. depends on oil production in the Gulf of Mexico for about 25% of our supply, according to the Department of Energy which is why the impact from Hurricane Katrina was so devastating.

Diminishing supply and rising demand suggests oil prices should continue to remain elevated. The rising motor vehicle usage in China (China Motor Vehicle Registration)
and India continues to influence the demand for oil.

Figure 2 Vehicle Registrations in China

Figure 2 and Figure 3 illustrate the rising use of motor vehicles in developing countries. This trends should continue and in turn, increase the demand for oil.

Figure 3 Automobile Sales in India

Maybe we should look to some leading countries in the development of alternative energy strategies. Perhaps we can learn from Norway’s HyNor Project. Solar photovoltaic projects being lead by Germany
and Spain.

So the next time you fill your tank or when you’re at your local food store and find that your wages don’t quite cover your food bill, ask your local Congressional representative for better planning on alternative energy strategies and solutions. Investment and research into solar, wind, electric vehicles, and hydrogen energy could provide real solutions by addressing energy needs, climate concerns, the environment, and food prices.

World oil demand continues to rise despite efforts to limit demand. Renewable energies such as solar and wind have the potential to limit our dependence on hydrocarbon fuels, but one issue remains prominent – storing energy. While the sun provides radiation for solar and generates wind, when its cloudy or dark we are unable to produce solar energy. One must provide a means to store that energy for when it is needed. Fuel cells enable energy conversion and fill a reliable role in alternative energy strategies.

A chart compiled by Wasserstoff-Energie-Systeme GmbH (h-tec) provides an easy to understand depiction of how fuel cells integrate with solar and wind energy solutions. Fuel cells provide the enabling technology that allows hydrogen to serve as the storage and transport agent. The solar energy that is produced during the daylight hours is used in an electrolyzer to produce hydrogen that in turn, is then used to operate the fuel cell producing electricity at night when it is needed. This process is called the solar-hydrogen energy cycle. Figure 1 illustrates the importance of energy storage in adopting alternative energies.

Figure 1 Solar-Hydrogen Energy Cycle

Demand for oil and hydrocarbon fuels continues to grow despite effort to conserve. Total Petroleum Consumption shows increasing oil demand from China and India while demand in the U.S. grows at a slower pace. With improving efficiencies and lower production costs, fuel cells could provide a solution to our appetite for oil in motor vehicles. Figure 2 describes how fuel cells and electrolyzers (fuels running in reverse) work.

Figure 2 Fuel Cells

Fuel cells are devices that convert chemical to electrical energy – in essence; it’s an electrochemical energy conversion device. In the chemical process of a fuel cell, hydrogen and oxygen are combined into water, and in the process, the chemical conversion produces electricity. In the electrolyzer, an electrical current is passed through water (electrolysis) and is the reverse of the electricity-generating process occurring in a fuel cell.

Hydrogen fuel cells offer tremendous opportunity for storing and transporting energy enabling broad applications for home, business, motor vehicle and large-scale energy projects. The follow provides a review of current technologies applicable to hydrogen fuel cells. Factors to consider in using hydrogen fuel cells include operating efficiency, operating temperature range, and material used for the electrolyte (the catalyst that separates hydrogen) and fuel oxidant (that transfers the oxygen atoms).

Figure 3 Hydrogen Fuel Cell Technologies

One of the most practical fuel cell technologies for motor vehicle use include Proton Exchange Membrane (PEM) because it operates at normal ambient temperatures and offers high electrical efficiency. There are several useful web sites that illustrate the benefits of hydrogen fuel cells. h-tec and the National Renewable Energy Laboratory provide some very useful information on hydrogen fuel cells.

We are also seeing progress on fuel cell vehicles that could ultimately ameliorate are demand for oil, if not eliminate it entirely, all with no carbon dioxide or other harmful emissions. We see most major automakers developing hydrogen powered fuel cell vehicles. GM is making progress introducing several models using GM’s Fuel Cell Technology.
Honda’s experimental hydrogen refueling station in Torrance, CA uses solar to produce hydrogen for their hydrogen fuel cell vehicle Honda’s FCX .

The bottom line is that the availability of cheap oil is on the decline and without further research on alternative energies we may find the global economy in a very tenuous position. Further research into solar and hydrogen fuel cells could significantly reduce our dependence on oil.

From the Industrial Revolution we learned that economic growth is inextricably linked to energy and as a result, our future is dependent upon equitable access to energy. When the Stourbridge Lion made entry as the first American steam locomotive in 1829 it was used to transport Anthracite coal mined in nearby Carbondale, PA to a canal in Honesdale that in turn linked to the Hudson River and onto New York City. Coal fueled the growth of New York and America’s Industrial Revolution because coal was cheap and more efficient than wood.

Advances in science and technology gave way to improvements in manufacturing, mining, and transportation. Energy became the catalyst to industrial growth. Steam power such as Thomas Newcomen’s steam powered pump in 1712 developed for coal mining and James Watt’s steam engine in 1765 were initially used to bring energy to market.

In terms of heating efficiency, coal at the time offered almost double the energy, pound for pound, in comparison to wood. Energy Units and Conversions KEEP Oil offers higher energy efficiencies over coal and wood, but as with most hydrocarbon fuels, carbon and other emissions are costly to our economy and environment.

With rapid growth in automobile production in the U.S., oil became the predominant form of fuel. According to the Energy Information Administration, in 2004 the U.S. spent over $468 billion on oil.

Figure 1 U.S. Energy Consumption by Fuel

We all need to become more conversant in understanding energy costs and efficiency and as a corollary, better understand the benefits of renewable energy such as solar, wind, and hydrogen fuel cells. A common metric we should understand is the kilowatt-hour (KWH) – the amount of electricity consumed per hour. The KWH is how we are billed by our local electric utility and can be used to compare costs and efficiency of hydrocarbon fuels and alternative energies.

One-kilowatt hour equals 3,413 British Thermal Units (BTUs). One ton of Bituminous Coal produces, on the average, 21.1 million BTUs, which equals 6,182 KWH of electric at a cost of about $48 per short ton (2,000 pounds). That means coal cost approximately $0.01 per KWH. To put that into perspective, a barrel of oil at $90/barrel distilled into $3.00 gallon gasoline is equivalent to 125,000 BTUs or 36.6 KWH of energy. Gasoline at $3.00/gallon equates to $0.08 per KWH. So gasoline at $3.00 per gallon is eight times more expensive than coal.

Is oil and gasoline significantly more efficient than coal? Let’s compare on a pound for pound basis. A pound of coal equates to about 10,500 BTUs or approximately 3.1 KWH per pound. A gallon of gasoline producing 125,000 BTUs weighs about 6 pounds equating to 6.1 KWH per pound (125,000 /3,413 /6). While gasoline is almost twice as efficient as coal, coal’s lower cost per KWH is why it is still used today to generate electric.

The Bottom Line: the economics of energy determines its use – coal still accounts for approximately half of our electric generation because it has a lower cost than other fuels. However, there are two factors to consider 1) the cost of carbon is not calculated into the full price of coal or other hydrocarbon fuels and 2) the cost of conventional fuel is calculated on a marginal basis while alternative fuel costs are calculated on a fixed cost basis. Meaning the cost of roads, trucks, and mining equipment is not factored into the price of each piece of coal, only the marginal cost of producing each ton of coal. For solar, hydrogen fuel cells, and wind energy systems, the cost to construct the system is factored into the total cost while the marginal cost of producing electric is virtually free. We need a framework to better measure the economics of alternative energy. The impact of carbon on our climate and global warming are clearly not measured in the costs of hydrocarbon fuels nor is the cost of protecting our access to oil such the cost the Iraq War.

Despite the carbon issues surrounding coal, (coal has higher carbon-to-hydrogen ratio in comparison to oil or gas) coal is more abundant and therefore is cheaper than oil. As electric utilities in 24 states embrace alternative energies through such programs as Renewable Portfolio Standards (RPS), perhaps the benefits of alternative energies will begin to combat the negative economics of hydrocarbon fuels.

Ethanol may emit less CO2 and help reduce the demand for foreign oil in the short term, but ethanol and in particular, corn-based ethanol raises food prices, is less efficient than gasoline, diesel, and biodiesel, and is not a substitute for oil.

According to research compiled by National Geographic Magazine , the energy balance of corn ethanol, (the amount hydrocarbon fuel required to produce a unit of ethanol) is 1-to-1.3 whereas for sugar cane ethanol the ratio is 1-to-8. This suggests corn-based ethanol requires significantly more energy to produce than sugar cane ethanol. Corn ethanol is only marginally positive.

A major issue with corn ethanol is its impact on corn prices and subsequently, food prices in general. It is the price of oil that is impacting the price of corn because nearly all ethanol produced in the U.S. is derived from corn. Therefore, corn prices are inextricably linked to oil prices as well as to the supply and demand of corn as food and feedstock. Corn Prices while volatile and impacted from weather and other variables appear to follow the rising price of oil as illustrated in Figure 1. In turn, corn prices are also influencing other commodity prices where corn is used for feed for livestock.

The rising motor vehicle usage in China and India is escalating the already tenuous situation in the oil markets. With ethanol tied to oil prices we are beginning to see corn prices exacerbate the inflationary pressures at the retail level. Over the last year consumers are paying more for food with large increases in the prices of eggs, cereal poultry, pork, and beef which are tied to corn.

Figure 1 Corn Prices

Senate legislation for Renewable Fuels Standard calls for ethanol production to increase to 36 billion gallons by 2022 with 21 billion derived from as cellulosic material such as plant fiber and switchgrass . Corn is expected to comprise 42% of the ethanol production in 2002 from virtually all today. The fact is that ethanol production at its current level of 6 billion gallons equates to only 4% of our gasoline usage and is already impacting food prices. Gasoline consumption in 2005 amounted to 3.3 billion barrels or 140 billion gallons. Current estimates put gasoline consumption at 144 billion gallons a year in 2007. Even if vehicles could run entirely on ethanol, there is not enough corn harvest to substitute our demand for oil. We need a cohesive and coordinated effort using multiple technologies to develop alternative energies to reduce our dependence on foreign oil.

Performance

According to Renewable Fuels Association ETHANOL FACTS:
ENGINE PERFORMANCE, ethanol offers higher engine performance with octane rating of 113 in comparison to 87 for gasoline and has a long history in the racing circuit. In 2007, the Indy Racing League, sponsors of the Indianapolis 500 started using ethanol in racecars. However, the higher engine performance may come at a cost of lower fuel efficiency.

Table 1 Specific Energy, Energy Density & CO2

Efficiency

Gasoline offers 56% higher energy efficiency (specific energy) over ethanol as measured by kilo-joules per gram (kj/g). (As a reference: 1 kilowatt-hour = 3,600 kilojoules = 3,412 British Thermal Units) Biodiesel with 35 kj/g is 33% more energy efficient than ethanol at 24.7 kj/g.

In terms of energy density, ethanol would require larger storage capacity to meet the same energy output of gasoline diesel, and biodiesel. Ethanol requires a storage tank 48% larger than gasoline and 41% larger than diesel for the same energy output.
Please see Hydrogen Properties and Energy Units

For a quick review of Specific Energy and Energy Density – (Molecular Weight Calculator) the specific energy of a fuel relates the inherent energy of the fuel relative to its weight and is measured in kilo-joules per gram.

CO2 Emission

The molecular weight of CO2 is approximately 44 with two oxygen molecules with an approximately weight of 32 and one carbon atom with a weight of 12. During the combustion process, oxygen is taken from the atmosphere producing more CO2 then the actual weight of the fuel. In the combustion process a gallon of gasoline weighing a little over six pounds produces 22 pounds of CO2.

CO2 emission is a function of the carbon concentration in the fuel and the combustion process. During combustion ethanol produces approximately 13 pounds of CO2 per gallon. Gasoline and diesel produce approximately 22 and 20 pounds per gallon, respectively. CO2 emissions per gallon appear quite favorable for ethanol. However, the results are less dramatic when CO2 emissions are compared per unit of energy produced.

Figure 2 CO2 per KWH

When measured in pounds of CO2 per kilowatt-hours (KWH) of energy, the results show ethanol producing 6% less CO2 than diesel or biodiesel and 5% less than gasoline. In the case of ethanol, the lower specific energy of the fuel negates the benefit of its lower CO2 emissions. Meaning more ethanol is consumed to travel the same distance as gasoline or diesel thereby limiting the benefit of its lower CO2 emissions.

The bottom line is ethanol does not ameliorate our dependence on foreign oil and while it demonstrates higher performance for racecars, it is still less efficient than gasoline diesel, and biodiesel, and diverts food production away from providing for people and livestock. The reality is there are special interest groups that obfuscate the facts about ethanol for their own benefit. The real solution to our imminent energy crisis is alternative energies including cellulosic ethanol, solar, hydrogen fuel cells, and wind.

Peak oil has been a discussion for several decades after the theory developed by Dr. M. King Hubbert was put forth to alert the world of the impending decline in oil production. Recent data from the Energy Information Administration (EIA) oil production from the twelve members of OPEC has declined from its peak in 2005, despite increased global drilling activity.

Figure 1 OPEC Oil Production

Higher oil prices is driven demand for energy exploration and drilling is up significantly in the U.S. and the world according to Baker Hughes Worldwide Rig Count. Oil price continue to remain above $90/barrel and despite the increased oil drilling activity, oil production remains relatively flat.

Figure 1 demonstrates the tenuous nature of OPEC oil production with oil production declining almost 4% from the peak average production of 31.2 million barrels per day. One must remember that oil production is variable with up and down trends over time. However, with oil over $900 a barrel we are not seeing significant production increase despite the rise in oil drilling. Figure 2 illustrates world-drilling rigs in comparison to oil prices on a global basis. The U.S. accounts for over half the world oil drilling rigs yet our production is less than 10% of total global production.

Figure 2 Rig Count and Oil Production

What does all this mean? For one peak oil may be a reality or sooner then we like. Secondly, with concern over climate change and global warming, there is no real spending on alternative energy to help mitigate a potential shortage in oil. More spending on solar and hydrogen fuel cells is required to ameliorate the eminent disruption in oil flow. Without an orchestrated government mandate to develop alternative energies all nations face a national security issue that has the potential to cripple economic activity.

Rising oil prices have driven exploration and drilling activity, yet oil production remains anemic in comparison. Could the latest data suggest oil production is nearing a peak? With global demand expected to rise over 30% by 2030 according to a recent article in the Wall Street Journal, Handicapping the Environmental Gold Rush the latest oil production figures suggest we are indeed vulnerable to energy shocks.

High oil prices have driven demand for energy exploration and investment into oil and gas drilling rigs. In the U.S., rig count is up 181% with 1,749 rigs in operation in 2007 from 622 in 1999 according to Baker Hughes Worldwide Rig Count. Oil prices are up quite dramatically in the last few weeks with latest price above $94/barrel.

Figure 1 Worldwide Rig Count and Oil Prices

Figure 1 illustrates world-drilling rigs in comparison to oil prices. The U.S. accounts for over half the world oil drilling rigs yet our production is less than 10% of total global production. While oil prices are nearly as high as they were back in the 70’s (accounting for inflation) we are not witnessing the tremendous oil-drilling explosion as we did back then.

Part of the explanation could lie with oil production. If we look at recent data, oil production appears to be leveling off while demand is expected to increase significantly as developing countries increase their use of motor vehicles. Data from the U.S. Department of Energy (DOE) and Ward’s Communications, Ward’s World Motor Vehicle Data show that the number of motor vehicle on the road is up 48% from 1990 to 2005 with countries like China experiencing the most dramatic increase. Yet oil production over this same period is up only 27%.

Figure 2 US Rig Count and Oil Production

In the U.S., rig count is up 118% from 1999, yet petroleum production is actually down 7%. On a global basis, oil and petroleum product production increased 13% since 1999 while global rig count increased 112%. The U.S. and the rest of the world is experiencing diminishing returns on investments in oil production wile usage, led by motor vehicle consumption continues to escalate. In the U.S. more than 60% of oil consumption goes to vehicle use.

With all of the attention given to oil and hydrocarbon fuels, alternative energies are just a small fraction of our energy needs. We need to dramatically increase our research efforts into alternative energies such as solar, wind, and hydrogen fuel cells energies.

After reviewing some of the details of Honda’s experimental solar-power hydrogen refueling station in Torrance, CA and its fuel cell vehicle several questions concerning efficiency and practicality come to mind. It most be noted that solar and hydrogen don’t emit harmful byproducts such as carbon dioxide or carbon monoxide so both technologies are important to our energy security. First let’s look at the efficiency of hydrogen and second the efficiency of generating hydrogen from solar.

As we learned from science class, hydrogen is the most abundant element in the universe. Hydrogen has approximately 3 times the energy per unit mass as gasoline and requires about 4 times the storage volume for a given amount of energy according to a Hydrogen Energy report from Stanford University. In further review of additional information on hydrogen we are also making some adjustments to our fuel-ranking table.

We are revising Table 1 that was used in our post of October 3, 2007 for data on the energy density for hydrogen from 2.5 kilowatt-hours (KWH) per gallon to 10.1 KWH/gal and is reflected in the revised Table 1 below. The discrepancy lies in measuring the weight of hydrogen in liquid volume. We are calculating the energy density of hydrogen using the high heat values of hydrogen of 61,000 British Thermal Units (BTUs) and a weight 0.57 pounds per gallon from the Stanford Hydrogen Report.

As a reference: 1 KWH = 3,600 kilojoules = 3,412 BTUs

Revised Table 1 Specific Energy, Energy Density & CO2

Hydrogen offers tremendous energy potential, but as we see from Table 1, hydrogen has a low energy density meaning it requires a large storage container to make it practical for use in a motor vehicle. Several car manufacturers including GM and Toyota have developed hydrogen vehicles. Hydrogen can be used in internal combustion engines replacing gasoline or in fuel cells to generate electric to power the vehicle. However, there are some limitations to the current technology that may limit the economic viability hydrogen powered vehicles in the near term. But there are no detrimental emissions with hydrogen as apposed to hydrocarbon fuels thus providing tremendous benefits as vehicle efficiency improves.

Honda’s solar-powered hydrogen fueling station takes nearly a week in sun to produce enough hydrogen to power Honda’s FCX concept hydrogen fuel cell vehicle. Honda employs a Proton Exchange Membrane Fuel Cell (PEMFC) that converts hydrogen to electric that in turn, powers the vehicle. The Honda FCX fuel cell vehicle has two fuel tanks that can be filled with up to 156.6 liters of hydrogen or about 43 gallons that offers 430km (267 miles) driving range. The hydrogen fuel cell vehicle provides a reasonable driving range, but with a fuel efficiency of 6.5 miles per gallon (MPG), suggests more research is needed.

BMW’s Hydrogen 7 can travel 125 miles on hydrogen and 300 on gasoline before refueling. In tests the BMW 745h liquid-hydrogen test vehicle has 75 kg tank has a Hydrogen Fuel Efficiency of 10 km/liter or about 25.2 MPG and cruising speed of 110 MPH. Not too bad for an internal combustion engine that is able to run on gasoline or hydrogen.

Figure 1 Specific Energy

Given the changes to hydrogen’s energy density we are also adjusting hydrogen density (Figure 2) to reflect liquid hydrogen and high-energy value as noted by Hydrogen Properties College of the Desert.

Revised Figure 2 Energy Density: KWH per Gallon

We still have more questions given hydrogen’s very high specific energy, (3 times that of gasoline) and low energy density (4 times the volume of gasoline). Hydrogen is more efficient then petroleum fuel, yet when used as a fuel cell in a vehicle Honda’s MPG of 6.5 MPG is quite low. The fuel efficiency of BMW’s Hydrogen 7 of 25.2 MPG is only at parity with gasoline.

The efficiency of using solar energy to generate hydrogen may not be the most efficient method. One report from Walt Pyle, Jim Healy, and Reynaldo Cortez Solar Hydrogen Production by Electrolysis indicated that a 1-kilowatt solar photovoltaic device could generate 1 cubic meter of hydrogen in 5.9 hours. Essentially, 5.9 KWHs from a 1KW solar cell produces 1 cubic meter of hydrogen. We know that a pound of hydrogen in liquid state equals approximately 61,000 BTUs (51,500 BTUs at low heat value) or 17.9 KWH.

Research at Caltech, suggests that photoelectrochemistry The Lewis Group may offer a more efficient means of generating hydrogen. We will continue to explore solar efficiency and hydrogen fuel cells to evaluate the economics of alternative energy.

The bottom line is that our dependence on foreign oil is the biggest threat to national security and without cultivation of alternative energies we continue to endure an untenable situation. Further research into solar and hydrogen fuel cells could significantly ameliorate our dependence on oil.

Despite efforts that have enabled the U.S. to limit its demand for oil, world oil demand is up significantly. Advances in technology such as solar energy and vehicle fuel cell could help the world reduce its dependence on oil.

Figure 1 Oil and Gold Prices

The U.S. Department of Energy (DOE) and the U.S. Environmental Protection Agency (EPA) today released the Fuel Economy Guide for 2008 model year vehicles Fuel Economy Leaders: 2008 Model Year Coming in first place is the Toyota Prius (hybrid-electric) with city/highway miles per gallon (MPG) of 48/45. With higher fuel costs more people are factoring in fuel efficiency into their purchase decision. However, it is the purchase of pickup trucks and SUV that account for most of the vehicle purchases in the U.S. and these vehicles are dramatically less fuel-efficient than hybrids and small four-cylinder automobiles.

Despite the trend towards larger vehicles, the U.S is not experiencing a rapid rise in oil demand. Yet oil prices continue to climb. While geopolitical risk may account for the bulk of the recent price increase, latest information from the U.S. Energy Information Administration (EIA) Total Petroleum Consumption shows increasing oil demand from China.

Figure 2 Oil Demand: U.S. and China

Figure 2 illustrates that while oil demand in the U.S. has grown only modestly since 2000, the growth in China’s oil demand is rising rapidly. The recent data from the EIA shows oil demand through Q2/07. The demand for oil in the U.S. is up 5% from 2000 while in China oil demand is up 59% over the same period.

Improving vehicle fuel efficiency may abate rapidly rising oil demand in the U.S., but more emphasis on diesel and hybrids could take us a lot further. For example, Toyota has been slow to introduce its diesel line of pickup trucks in the U.S. while it offers a broad line of more fuel-efficient vehicle outside the U.S. Toyota offers several cars and trucks in Europe with impressively high fuel efficiencies that are not available in the U.S. Infact, the Toyota Hilux two-wheel drive pickup truck offers a four-cylinder diesel engine with an MPG of 44.8 on the highway and 29.1 in the city.

We are also seeing progress on fuel cell vehicles that could ultimately ameliorate are demand for oil, if not eliminate it entirely, all with no carbon dioxide or other emissions. We see most major automakers developing hydrogen powered fuel cell vehicles. Honda for one has the right concept in employing solar energy to make hydrogen.

Honda’s experimental hydrogen refueling station in Torrance, CA increases the solar incre3ases the efficiency of hydrogen fuel by using solar energy to produce hydrogen. The hydrogen is then used to power Honda’s Honda’s FCX concept hydrogen fuel cell vehicle with the only emission being pure water vapor. These fuel cell vehicles may not be ready for prime time, they provide a clear reality to what is achievable.

The bottom line is that supply and demand dictate price and the availability of cheap oil is on the decline. Further research into solar and hydrogen fuel cells could significantly change our dependence on oil.

With the rapid growth in vehicle use around the world, it would be nice to know what are the most efficiency, economic, and least carbon emitting fuels. The number of motor vehicles on the road is increasing rapidly. The number of cars and trucks in China is up over 3,600 percent in the last thirty years. Data from the U.S. Department of Energy (DOE) and Ward’s Communications, Ward’s World Motor Vehicle Data provide an interesting view of the growth in motor vehicle use.

Figure 1 China Truck and Car Registration

While the U.S. still accounts for the largest motor vehicle market, the rest of the world is quickly accelerating towards more vehicles on the road. Figure 2 shows the number of vehicle registrations over the last thirty years for China, the U.S. and the rest of the world (ROW). Vehicle registration growth in the U.S. has been growing at a 2% per year rate from 1975 to 2005. The largest growth in vehicle registration is in China and India where growth in the last ten years is up 195% and 99%, respectively.

Figure 2 World Vehicle Registration

With an explosion in motor vehicle use, what fuel should we be using to better performance and reduce emissions? Let’s go back to two basic concepts of energy: Specific Energy and Energy Density. For a quick review, (Molecular Weight Calculator) the specific energy of a fuel relates the inherent energy of the fuel relative to its weight. Specific energy is often measured in kilo-joules per gram (kj/g). One kilo-joule equals one kilowatt-second meaning one kilowatt-hour (KWH) equals to 3,600 kilo-joules. Also one British Thermal Unit (BTU) equals 1,055.05585 joules. A reference to the specific energy and energy values of most fuels can be found at Hydrogen Properties

Figure 3 Specific Energy

By specific energy hydrogen is the clear leader. However, vehicles must inherently carry their fuel supply, so to determine which fuel is best for motor vehicles, energy density of the fuel is the next measurement. While vehicle fuel efficiency is dependent upon a number of factors such as engine type and performance, make and model of vehicle, road conditions and fuel, we are focusing on fuel energy.

Figure 4 Energy Density: KWH per Gallon

Figure 4 illustrates how fuels compare with respect to energy density, that is, energy relative the container size. We again are using KWH to measure energy value. Hydrogen, because it is so light, requires 15.9 times the container volume to provide the same energy as diesel. Biodiesel provides more power per gallon than Ethanol, which requires 1.6x, the container size for the same amount of energy as diesel. Biodiesel and diesel are relatively similar with respect to energy density. While both Ethanol and Biodiesel are both form of renewable energy, Biodiesel offers more bang per gallon. Before we are able invest more into hydrogen and solar energy to bring alternative energy into parity with conventional hydrocarbon fuels, diesel and biodiesel offer better energy efficiency among hydrocarbon fuels.

Table 1 Specific Energy, Energy Density & CO2

As a final assessment of hydrocarbon fuels, let’s compare carbon dioxide (CO2) emissions among our list of fuels. CO2 emission is a function of carbon concentration and combustion process of the fuel. Fuel energy research at the Department of Environmental Protection (EPA) and DOE indicate 99% to nearly 100% combustion of with fuels used in vehicles. That means almost all of the atoms in the fuel are converted to either heat or byproducts such as CO2.

Figure 5 illustrates how much CO2 is produced per gallon of fuel. Remember the molecular weight of CO2 is about 44 with oxygen contributor nearly 73% of the weight and is taken from our atmosphere during combustion. This is why more CO2 is created than the actual weight of the fuel. A second factor needs to be considered when evaluating CO2 emission and that is how much CO2 is produced per energy value. In comparing CO2 emissions per KWH of energy, Ethanol produces about 7% less CO2 than diesel or Biodiesel and 5% less than gasoline. Neither of these estimates considers the emissions from the processing to produce Ethanol or Bioiesel.

Figure 5 CO2 per Gallon

The bottom line is Ethanol and Biodiesel provide marginal relief to our energy crisis with biodiesel offering better efficiency and Ethanol marginally less CO2 missions. The only real solution to our imminent energy crisis is alternative energies such as solar, hydrogen fuel cells, and wind.

With rising energy prices and growing concern over global warming, will advances in solar and alternative energies enable the development of affordable and efficient energy solutions. Caltech research on the energy conversion process may offer some insight.

Energy conversion, ways of converting sunlight to electric and chemical energy, offers promising advancements to make solar and hydrogen energies more practical and affordable. On the forefront of energy conversion research, the framework of developing disruptive energy technologies, is The Lewis Group, that is part of the California Institute of Technology’s division of Chemical and Chemical Engineering. The Lewis Group is working in several research areas some geared towards to better understanding of energy capture, conversion of light into electrical and chemical energy, and energy storage. These research projects include photo-electrochemical, which focuses on the chemistry of semiconductors and materials, surface modification of semiconductors to improve electrical properties, and nanocrystalline titanium dioxide that could potentially lead to significantly lower cost for converting sunlight to electrical energy. The Lewis Group research projects are much more than improving photovoltaic devices; they are also exploring ways to convert sunlight into stored fuel energy.

While we are providing a brief and very oversimplified view of the solar energy research, it is important to understand the dynamics of energy conversion because the conversion process impacts the efficiency and the production cost of photovoltaic (PV) devices and fuels cells. The Lewis Group has an interesting PowerPoint presentation available for download providing an overview of energy from consequences of CO2 emissions to the latest in new technologies to improve alternative energies. Of particular interest are the historical efficiency trends for various materials used in crystalline and thin-film solar cells, energy conversion strategies of turning light to fuel and electric, and the cost/efficiency tradeoff in photovoltaic devices.

Cost/Efficiency Tradeoff
Photovoltaic devices are limited in their practical efficiencies governed by the thermodynamic limits and production costs that involve tradeoffs in materials, production processes, and PV device packaging. The Lewis Group provides a thorough illustration of the efficiency trends for various PV devices materials such as crystalline silicon used in semiconductors as well as the new approaches to thin film PV including amorphous silicon, cadmium telluride (CdTe), copper indium deselenide (CIS) and copper indium gallium deselenide materials (CIGS). These thin film material could offer substantial PV devices price reductions as a result of higher efficiency or lower production costs.

Figure 1 Cost/Efficiency Tradeoff

There is a tradeoff between improving the efficiency of a PV device, that is the amount of electric energy per solar panel, and the cost to produce the PV device. The average efficiency for a PV device is between 15%-to-16% and the average cost between $100-to-$350 a square meter. The cost per square meter and PV efficiency measured in watts per square meter can equate to a cost per watt, which ranges from $1.25/watt to $2.00/watt. SunPower (SPWR), offers the leading PV single junction device efficiency of 22% employing crystalline silicon and is expected to reach 500 megawatts (MW) production capacity by late 2009 from 330 MW in 2007. First Solar (FSLR) is ramping its thin film cadmium telluride (CdTe) solar technology by leveraging its low cost advantage with high volume production with its 75 MW in operations Ohio and 100 MW coming online in Germany. Startup Nanosolar is focusing on thin film solar PVs with a blend of copper indium gallium deselenide (CIGS) materials along with a manufacturing process much like printing, by placing the material blend upon metal foil. Evergreen Solar (ESLR) employs an integrated manufacturing process from wafers to cells and panels based on its proprietary String Ribbon Wafer technology with production levels at 118 MW in 2007.

There is presently a practical limit to solar efficiencies of approximately 30% and a thermodynamic limit of about 83%. The Shockley-Queisser limit at 30% for single junction solar cell efficiency is a function photon absorption in a material. “Detailed Balance Limit of Efficiency of p-n Junction Solar Cells” (W Shockley and HJ Queisser, Journal of Applied Physics, 1961) found that photons delivering excitation energy above a threshold (the band gap) for charge carrier electrons is lost to heating, meaning excess photon energy generates heat and not electric current. Photons with energy levels below the band gap pass through the material and photons above the threshold are absorbed. The absorbed photons transfer their energy to excite the electrons in the material and create pairs of negative electrons and positive charges that, because of their repulsion, travel to opposite ends thereby generating electric current.

According to the Lewis Group, other factors that limit PV cell efficiency include reflective loss of approximately10% for a material like silicon and a fill factor constraint that peaks at 83%. The fill factor restraint is attributable to the current-voltage characteristics of a PV cell that deals with matching the photocurrent density and voltage.

NREL (DOE lab) and Spectrolab (a Boeing company BA) using a multijunction semiconductor approach along with solar concentrators have achieved solar cell efficiencies of 40.7% in lab experiments while commercial products operate at 26.5%-to-28.3% efficiency range. Solar cell suppliers could reduce costs through production improvements or improve PV efficiencies without adding to costs. PV cell suppliers should benefit from economies of scale to reduce production costs while advances in technology improve PV efficiencies.

Research conducted by the Lewis Group at Caltech indicates that materials selected for PV devices have unique properties in their ability to absorb sunlight and generate electricity. In their analysis of semiconductor materials, the Lewis Group research found two parameters, determined by the physical properties of the material, that influence the PV’s efficiency. One is the thickness of the material, measured in microns, required to absorb enough sunlight to bring particular atoms in the material to an excited state, thereby freeing the electron to generate an electric current. The second parameter in the PV material is length of time the excited electrons last before recombining to generate heat instead of electric. Some materials such as silicon require material thickness of 100 microns while gallium arsenide (GaAs) only 1-to-3 microns.

Energy Conversion
Conversion of energy into electric or fuel is advancing through research in photoelectrochemical materials for solid and liquid fuels. Improvements in efficiencies for PV devices and fuel cells offer tremendous potential for transportation and home electric use.

Figure 2 Efficiency of Photovoltaic Devices

From figure 2, it seams quite apparent that PV efficiency has improved substantially since the 1950’s. Please see the Department of Energy (DOE) Basic Research Needs for Solar Energy Utilization for detailed analysis of solar energy. Further progress in PV and fuel cell technologies is predicated upon successful funding of further research. The bottom line is that only through innovative research will a truly disruptive technology be developed that has the ability of changing the economics to deliver an energy solutions to all nations.

Without greater investment into solar and hydrogen energies, we are held hostage to rising oil prices. Alternative energies such as solar and hydrogen fuel cells offer tremendous potential to provide energy independence and energy security. The dependence of the U.S. upon imported foreign oil raises inflation, weakens our currency, exacerbates the trade deficit, and forces consumers to pay higher prices for home heating and transportation. With oil exceeding $80 a barrel in late September 2007, the only beneficiaries are countries exporting oil and oil conglomerates. I guess when countries such as Dubai, after accumulating a large trade surplus based on inflated oil prices, decides to diversify away from oil and buy a non-voting stake in the NASDAQ market, it’s a wake-up call.

To better understand the potential of alternative energy, we should try to understand two basic concepts of energy: Specific Energy and Energy Density. Without digressing into chemistry 101, (Molecular Weight Calculator) the specific energy of a fuel relates the inherent energy of the fuel relative to its weight. Typically, specific energy is measured in kilo-joules (kj) per gram. A joule is a measure of kinetic energy – one joule is the amount of energy needed to move two kilograms at a velocity of one meter per second. Or a kilo-joule equals one kilowatt-second meaning one kilowatt-hour (KWH) equals to 3,600 kilo-joules. Your local electric utility bills you by the KWH, which according to the US Department of Energy Average Retail Price of Electricity in 2007 is approximately $0.11 per KWH.

Table 1 Specific Energy and Energy Density

The specific energy of a fuel tells us how much energy can be derived from a measured amount fuel by weight. By ranking each fuel by its specific energy, one can determine how efficient each fuel is. Specific energy and fuel density are often proportional to the ratio of carbon and hydrogen atoms in the fuel. A reference to the specific energy and energy values of most fuels can be found at Hydrogen Properties

Figure 1 Specific Energy
Figure 1 illustrates how fuels compare according to their specific energy. As we can see, hydrogen, because it’s extremely light, has the highest specific energy in comparison to hydrocarbon fuels.

This however, is not the full story because volume or energy storage requirement becomes a significant factor for gaseous fuels. Specific energy is important to analyze fuel efficiency by weight, but for hydrogen that must be pressurized and cooled to bring to a liquid state, the energy density become more relevant to fuel efficiency.

Figure 2 Energy Density: KWH per Gallon

Figure 2 illustrates how fuels compare according to their energy density, that is, energy relative the container size. As we can see from figure 2, hydrogen, because it is so light, requires 15.9 times the container volume to provide the energy of diesel or oil. In comparison to diesel, ethanol requires 1.6x the container size for the same amount of energy.

The container size becomes a significant detriment for housing hydrogen. Energy density is usually measured in kilo-joules per cubic meter (kj/m3). As kilo-joules are readily translated into KWH by multiplying by the number of seconds in an hour (3,600) and the College of the Deserts’ computation into gallons, we are converting the data into KWH per gallon for those of us in the U.S.

Hydrogen fares poorly relative to energy density. However, technology offers an approach to enhance the benefits of hydrogen with fuel cells. Fuel cell enable hydrogen molecules to interact with oxygen through a membrane that allows transmission in only one direction to convert H2 into an electric current to power your automobile. Fuel Cell Basics Fuel cells often capture the hydrogen electron from hydrocarbon fuel such as methane allow convention fuels to generate hydrogen for electric generation.

In a hydrogen-based economy, solar energy can provide electric to generate hydrogen through electrolysis and vice versa. Jeremy Rifkin’s The Hydrogen Economy eloquently illustrated the hydrogen economy where fuel cell act as mini power plants and the electric network resembles the Internet where cars plug into an electrical grid supplemented by solar cells at your home and work. Electric power generation moves from large utility generation to a distributed generation – everyone plugged in can generate power to the grid. The key benefit of hydrogen is that it democratizes the energy economy bringing power to all countries in the world.

An interesting technical analysis of hydrogen energy is provided by Ulf Bossel and Baldur Eliasson Energy and the Hydrogen Economy The bottom line is that solar and hydrogen energies offer tremendous potential to low long-term fuel costs and improve our environment and climate. More research is required to lower costs and improve feasibility.